Binding properties of synthesized CS glasses activated by alkaline components

Authors

DOI:

https://doi.org/10.54355/tbus/4.3.2024.0064

Keywords:

low basic tobermorite-like hydrosilicates, heat and humidity treatment, alkaline components, differential thermal analysis, slag-alkali binders, hydration

Abstract

The paper presents the synthesis and evaluation of hydration and binding properties of individual minerals with glass-like structures in silicate systems, most often found in technogenic materials based on phosphorus and blast furnace slags. This work aims to determine the optimum composition of CS glasses to obtain binders with given properties, the hydration of glasses of different silicate and aluminosilicate compositions in the presence of solutions of soda, sodium hydroxide, and sodium metasilicate was investigated. The results of X-ray phase and differential-thermal analysis, and infrared spectrum are given, and the hydration structure of the calcium oxide-silicon oxide-alkali component system has been studied. The analysis of hydrate neoplasms of the studied binding systems shows that the most optimal conditions for the synthesis of stone strength with stable physical and mechanical properties are created in the presence of gel-like phase reinforced by hydrosilicates and hydroaluminosilicates of alkaline and alkaline-alkaline-earth composition, characterized by fiber-like structure and possessing the ability to epitaxial fusion with each other, as well as gel-like phase, which they reinforce.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

References

P. P. Budnikov and V. L. Pankratov, “Hydraulic activity of monocalcium silicate and helenite,” in Chemistry and technology of silicates, Kiev: Naukova dumka, 1964, pp. 375–382.

P. P. Budnikov, B. C. Gorshkov, and T. A. Khmelevskaya, “Assessment of the astringent properties of slags according to their chemical and mineralogical composition,” in Chemistry and technology of silicates, Kiev: Naukova dumka, 1964, pp. 446–457.

P. P. Budnikov and B. C. Gorshkov, “Investigation of hydrated synthetic minerals of alumina slags,” in Chemistry and technology of silicates, Kiev: Naukova dumka, 1964, pp. 437–445.

S. Kucharczyk et al., “Structure and reactivity of synthetic CaO-Al2O3-SiO2 glasses,” Cem Concr Res, vol. 120, pp. 77–91, Jun. 2019, doi: 10.1016/j.cemconres.2019.03.004. DOI: https://doi.org/10.1016/j.cemconres.2019.03.004

S. Machida, K. Katsumata, K. Maeda, and A. Yasumori, “Effect of Vanadium Oxide on the Crystallization of CaO–Al 2 O 3 –SiO 2 Glass,” ACS Omega, vol. 8, no. 9, pp. 8766–8772, Mar. 2023, doi: 10.1021/acsomega.2c08246. DOI: https://doi.org/10.1021/acsomega.2c08246

S. Machida, K. Maeda, K. Katsumata, and A. Yasumori, “Microstructural Control of CaO–Al 2 O 3 –SiO 2 Glass Ceramics by Oxidation and Mixing with Nucleation Agents,” ACS Omega, vol. 7, no. 37, pp. 33266–33272, Sep. 2022, doi: 10.1021/acsomega.2c03799. DOI: https://doi.org/10.1021/acsomega.2c03799

M. M. Sychev, Hardening of binders. L: Stroyizdat, 1974.

B. K. Sarsenbayev, Z. A. Estemesov, J. T. Aimenov, N. B. Sarsenbayev, and A. J. Aimenov, Slag-alkali binding concretes. Shymkent, 2016.

Downloads

Published

2024-09-30

How to Cite

Sarsenbayev, B., Auyesbek, S., Begentayev, M., Sarsenbayev, N., Khaltursunov, E., & Sauganova, G. (2024). Binding properties of synthesized CS glasses activated by alkaline components. Technobius, 4(3), 0064. https://doi.org/10.54355/tbus/4.3.2024.0064

Issue

Section

Articles

Categories